The pseudo three-component reaction has been investigated using available materials, including various aromatic/aliphatic aldehydes, acetoacetanilide and (DBU) as a strong base for the formation of highly substituted cyclohexanones[5.4.0] The catalyst used as a green organic catalyst was cheap, available and efficient, and the desired products were obtained with high yield[5.4.0] The reaction is carried out at [5.4.0][5.4.0] °C in solvent-free conditions[5.4.0] Among the features introduced in this research, we can mention the short reaction time, simple and easy separation of the products in the synthesis of this group of highly substituted cyclohexanones[5.4.0] The synthesized products have been identified using 1H, 13C NMR, FT-IR and mass spectrometry methods[5.4.0]The pseudo three-component reaction has been investigated using available materials, including various aromatic/aliphatic aldehydes, acetoacetanilide and (DBU) as a strong base for the formation of highly substituted cyclohexanones [5.4.0] The catalyst used as a green organic catalyst was cheap, available and efficient, and the desired products were obtained with high yield[5.4.0] The reaction is carried out at [5.4.0][5.4.0] °C in solvent-free conditions[5.4.0] Among the features introduced in this research, we can mention the short reaction time, simple and easy separation of the products in the synthesis of this group of highly substituted cyclohexanones[5.4.0] The synthesized products have been identified using 1H, 13C NMR, FT-IR and mass spectrometry methods[5.4.0]